Cellulose derivative as protection coating: Effect of nanoparticle additives on load capacity
DOI:
https://doi.org/10.24036/teknomekanik.v5i2.16372Keywords:
Load capacity, Nanoparticle additive, Cellulose composite, CoatingAbstract
The cellulose derivative hydroxypropyl methylcellulose (HPMC) has recently been extensively studied and used in mechanical applications. However, the softness and susceptibility to deformation of HPMC limited its further applications. In this study, metal nanoparticles (nano-aluminum and nano-copper) and nano-metal oxide particles (nano-alumina and nano-copper oxide) were used as additives to HPMC to form a composite film with improved mechanical properties, particularly load capacity. The addition of high levels of additives provided a higher load capacity. Among the nano-additives used in the study, Cu (2 wt.%) provided the composite with the highest load capacity, improving the load capacity of pure HPMC by 250%. The surface treatment of strengthening additives is an important step. Adding specific high-strength and high-modulus metal and metal oxide additives to the soft HPMC matrix can effectively improve the load-bearing capacity of the composite material. This study proposes a simple evaluation method for the load-bearing capability of the coating as well.
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B. B. Boonstra, “Role of particulate fillers in elastomer reinforcement: a review,” Polymer, vol. 20, no. 6, pp. 691–704, Jun. 1979, https://doi.org/10.1016/0032-3861(79)90243-X
N. Kida, M. Ito, F. Yatsuyanagi, and H. Kaido, “Studies on the structure and formation mechanism of carbon gel in the carbon black filled polyisoprene rubber,” J Appl Polym Sci, vol. 61, no. 8, pp. 1345–1350, Aug. 1996, https://doi.org/10.1002/(SICI)1097-4628(19960822)61:8<1345::AID-APP15>3.0.CO;2-Y
S. C. Shi, T. H. Chen, and P. K. Mandal, “Enhancing the Mechanical and Tribological Properties of Cellulose Nanocomposites with Aluminum Nanoadditives,” Polymers 2020, Vol. 12, Page 1246, vol. 12, no. 6, p. 1246, May 2020, https://doi.org/10.3390/polym12061246
S. C. Shi and X. X. Zeng, “Effect of the strengthening mechanism of SiO2 reinforced poly(methyl methacrylate) on ductility performance,” Journal of Polymer Research 2022 29:10, vol. 29, no. 10, pp. 1–9, Sep. 2022, https://doi.org/10.1007/S10965-022-03259-0
T. Jiang, T. Kuila, N. H. Kim, B. C. Ku, and J. H. Lee, “Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites,” Compos Sci Technol, vol. 79, pp. 115–125, Apr. 2013, https://doi.org/10.1016/j.compscitech.2013.02.018
K. P, S. v S, and B. N. Narayanan, “Ball-Mill Assisted Green One-Pot Synthesis of ZnO/Graphene Nanocomposite for Selective Electrochemical Sensing of aquatic pollutant 4-nitrophenol,” Teknomekanik, vol. 4, no. 2, pp. 64–71, Oct. 2021, https://doi.org/10.24036/teknomekanik.v4i2.10872
J. L. Ardi, H. Nurdin, A. Arafat, and S. R. P. Primandani, “Analysis of Tensile Strength of Citronella (Cymbopogon Nardus) Fiber Reinforced Composite Materials,” Teknomekanik, vol. 4, no. 2, pp. 72–77, Oct. 2021, https://doi.org/10.24036/teknomekanik.v4i2.10472
S. C. Shi and F. I. Lu, “Biopolymer Green Lubricant for Sustainable Manufacturing,” Materials 2016, Vol. 9, Page 338, vol. 9, no. 5, p. 338, May 2016, https://doi.org/10.3390/ma9050338
S. C. Shi and T. F. Huang, “Raman study of HPMC biopolymer transfer layer formation under tribology test,” Optical and Quantum Electronics 2016 48:12, vol. 48, no. 12, pp. 1–9, Nov. 2016, https://doi.org/10.1007/S11082-016-0807-4
S. C. Shi and Y. Q. Peng, “Preparation and tribological studies of stearic acid-modified biopolymer coating,” Prog Org Coat, vol. 138, p. 105304, Jan. 2020, https://doi.org/10.1016/j.porgcoat.2019.105304
S. C. Shi and J. Y. Wu, “Deagglomeration and tribological properties of MoS2/hydroxypropyl methylcellulose composite thin film,” Surf Coat Technol, vol. 350, pp. 1045–1049, Sep. 2018, https://doi.org/10.1016/j.surfcoat.2018.02.067
S. C. Shi and C. C. Su, “Electrochemical behavior of hydroxypropyl methylcellulose acetate succinate as novel biopolymeric anticorrosion coating,” Mater Chem Phys, vol. 248, p. 122929, Jul. 2020, https://doi.org/10.1016/j.matchemphys.2020.122929
S. C. Shi, “Hydroxypropyl Methylcellulose Phthalate Biopolymer as an Anticorrosion Coating,” Int J Electrochem Sci, vol. 16, pp. 1–10, 2021, https://doi.org/10.20964/2021.09.44
S. C. Shi and T. F. Huang, “Effects of temperature and humidity on self-healing behaviour of biopolymer hydroxylpropyl methylcellulose for ecotribology,” Surf Coat Technol, vol. 350, pp. 997–1002, Sep. 2018, https://doi.org/10.1016/j.surfcoat.2018.03.039
S. C. Shi and S. Z. Jiang, “Influence of graphene/copper hybrid nanoparticle additives on tribological properties of solid cellulose lubricants,” Surf Coat Technol, vol. 389, p. 125655, May 2020, https://doi.org/10.1016/j.surfcoat.2020.125655
S. C. Shi, X. N. Tsai, and S. S. Pek, “Tribological behavior and energy dissipation of hybrid nanoparticle-reinforced HPMC composites during sliding wear,” Surf Coat Technol, vol. 389, p. 125617, May 2020, https://doi.org/10.1016/j.surfcoat.2020.125617
S. C. Shi and J. H. C. Yang, “Preparation of stable biopolymer composite suspension with metal/metal-oxide nanoparticles,” Modern Physics Letters B, vol. 34, no. 7–9, Mar. 2020, https://doi.org/10.1142/s021798492040028x
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